Rapunzel/Rachel – Diana Agron.
 

Flynn Rider (Eugene)/Dean – Jensen Ackles.
 

Mother Gothel/Gothel – Idina Menzel.

Pascal/Patch – Mark Salling.
 

Maximus/Max – Jared Padalecki.
 

Giselle/Elle – Karen Gillan. 
 

Príncipe Edward/Edward – Santiago Cabrera.
 

Nathaniel/Nathan – Danny DeVito. 
 

Reina Narissa/Narissa – Monica Bellucci.